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Hydrogen

Hydrogen

Hydrogen production is a complex process involving various chemical reactions, and the quality and purity of the hydrogen gas generated are of utmost importance. To safeguard the integrity and safety of the produced hydrogen gas, the application of analytical solutions is essential. These solutions play a crucial role in monitoring the gas’s purity, quality, and overall production process. In this article, we will explore the reasons why analytical solutions are indispensable in hydrogen production and how they contribute to achieving optimal efficiency, safety, and adherence to industry standards.

Hydrogen gas possesses high flammability and explosiveness, making the presence of impurities or contaminants in the gas stream potentially hazardous. By utilizing analytical solutions, operators can continuously monitor the purity and quality of the hydrogen gas. This proactive approach enables the timely detection and identification of any impurities or contaminants present, effectively reducing the risk of fire or explosion and ensuring a safe production environment.

The efficiency of hydrogen production processes can be influenced by several factors, including feedstock composition, reaction conditions (temperature and pressure), and the presence of impurities or contaminants. Analytical solutions offer real-time monitoring capabilities, allowing operators to closely observe and analyze these parameters. By leveraging this data, they can optimize the production process, fine-tuning it to achieve maximum efficiency and yield.

Hydrogen gas finds extensive application across a wide range of industries, including fuel cells, refining, and chemical production. For seamless integration into these applications, maintaining the highest quality standards is imperative. Analytical solutions play a pivotal role in quality control, ensuring that the hydrogen gas meets the required specifications and industry standards. By employing rigorous monitoring techniques, our solutions guarantee consistent quality, enabling reliable and efficient operation in various industrial processes.

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FUEL CELL HYDROGEN

Fuel cell hydrogen quality is of paramount importance in ensuring the optimal performance and longevity of fuel cell systems. High-quality hydrogen typically refers to hydrogen that meets stringent purity and cleanliness standards. Impurities such as moisture, carbon monoxide, sulfur compounds, and particulate matter must be meticulously removed to prevent catalyst poisoning and degradation of fuel cell components. Additionally, hydrogen quality relates to its pressure and temperature, which must be within specified ranges for efficient operation. Achieving consistent and high-quality hydrogen is crucial for various applications, including transportation and stationary power generation, as it directly impacts the efficiency, reliability, and environmental benefits of fuel cell technology. Stringent quality control measures and standards are in place to guarantee that the hydrogen used in fuel cells meets these rigorous criteria, ensuring the continued advancement and adoption of this clean energy technology.

Our TIGER OPTICS™ CRDS (Cavity Ring-Down Spectroscopy) gas analyzers are specifically designed for fuel cell hydrogen production, providing accurate measurements of hydrogen purity and impurities in the gas stream (hydrogen purity to meet ISO14687/SAE J2719 standards).  These advanced analyzers excel at detecting impurities at trace levels, reaching concentrations as low as parts-per-billion (ppb) or even parts-per-trillion (ppt). With their remarkable selectivity and exceptional detection limits, our CRDS gas analyzers effectively identify and quantify impurities that may affect fuel cell performance and durability. Continuous monitoring of impurities allows fuel cell operators to ensure compliance with purity standards, optimize fuel cell operation, extend the lifespan of components, and enhance the overall efficiency and reliability of the system.

Similarly, our EXTREL™ Quadrupole Mass Spectrometers are ideal for monitoring hydrogen purity and impurities in fuel cell hydrogen production. These mass spectrometers offer unparalleled sensitivity and precision in detecting and quantifying various impurities, including trace gases and volatile organic compounds (VOCs). By analyzing the mass-to-charge ratio of ions, our Quadrupole Mass Spectrometers can identify impurities at incredibly low concentrations, enabling real-time monitoring and analysis. This capability empowers fuel cell operators to ensure that the hydrogen gas stream meets stringent purity requirements, identify and address potential sources of contamination, optimize purification processes, and maintain a consistently high-quality hydrogen supply for efficient and reliable fuel cell operation.

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HYDROGEN PRODUCTION

Hydrogen Production plants around the world regularly choose our EXTRELMAX300-RTG™ Industrial Process Gas Analyzer for their analysis requirements. Because of the MAX300-RTG’s speed and ability to analyze multiple streams, it has become the system of choice to obtain accurate heating value analysis for product quality control, and to maximize revenue.

Producers are purchasing the MAX300-RTG for providing a full composition analysis of natural gas or feed stream in less than 10 seconds.

Advantages includes:

  • The ability to perform real-time compositional analysis and calculate heating values of the process feed gas
  • C1-C8 analysis which can be performed in less than 10 seconds
  • The capability to analyze over 160 streams
  • Stream-switching capabilities allowing the operator to quickly analyze additional process streams such as reformer effluent, tail gas and the recycle streams
  • Use of the optional Electron Multiplier Detector which provides part per million (ppm) level analysis of the combined nitrogen and carbon monoxide components in the hydrogen product purity stream

GREEN HYDROGEN PRODUCTION

Green hydrogen production is a cutting-edge and environmentally responsible process that holds immense promise for a sustainable future. It involves the production of hydrogen gas using renewable energy sources, typically through the process of water electrolysis, where electricity generated from clean sources, such as wind or solar power, splits water molecules into hydrogen and oxygen. What sets green hydrogen apart is its minimal environmental impact. It produces no greenhouse gas emissions, making it a key player in the transition to a low-carbon economy. Green hydrogen has a wide range of applications, from fueling clean transportation to storing renewable energy and decarbonizing industrial processes. As the world seeks cleaner and more efficient energy solutions, green hydrogen production is emerging as a pivotal technology in the fight against climate change and the pursuit of a more sustainable energy landscape.

TRANSPORTING HYDROGEN

Transporting hydrogen is a critical aspect of integrating this versatile energy carrier into our sustainable energy systems. Hydrogen can be transported in several forms, including gas pipelines, liquefied hydrogen (LH2) in cryogenic tanks, and chemical compounds like ammonia, which can be converted back into hydrogen at the destination. Pipeline transportation is efficient for short to medium distances, while liquefied hydrogen is suitable for longer journeys, such as intercontinental shipping. The challenge lies in minimizing energy losses during transportation and ensuring safety, as hydrogen is highly flammable. Advances in materials science and safety protocols are continually improving the efficiency and reliability of hydrogen transport, making it a crucial component of the hydrogen economy, enabling the distribution of clean energy to various sectors such as industry, transportation, and power generation.

PROCESS CONTROL

Hydrogen process control plays a pivotal role in ensuring the safe, efficient, and reliable production, storage, and utilization of hydrogen across various applications. It involves the implementation of sophisticated monitoring and automation systems to regulate critical parameters such as pressure, temperature, flow rates, and composition throughout the hydrogen supply chain. Tight control is essential to prevent safety hazards, ensure product quality, and maximize process efficiency. Advanced technologies like sensors, control algorithms, and data analytics are employed to maintain precise control over hydrogen production, purification, storage, and distribution processes. Effective process control not only enhances the safety and performance of hydrogen systems but also contributes to the broader goal of integrating hydrogen as a clean energy carrier, making it a key element in the transition to a sustainable and low-carbon energy landscape.

Our EXTREL™ MAX300-RTG™ 2.0 Mass Spectrometer is a highly sensitive and accurate analytical instrument that is specifically designed for the analysis of gas samples. This instrument is often used in the hydrogen production industry due to its ability to provide real-time monitoring of gas streams and its high sensitivity for trace impurity detection.  

HyCO PLANT

A HyCO plant is a facility that produces both hydrogen (H2) and carbon monoxide (CO) through a process known as steam methane reforming (SMR). In a typical HyCO plant, natural gas (methane, CH4) is combined with steam (H2O) in the presence of a catalyst at elevated temperatures to undergo the SMR reaction, which produces hydrogen and carbon monoxide. This mixture of hydrogen and carbon monoxide, often referred to as synthesis gas or syngas, has various industrial applications.

The syngas produced in a HyCO plant can be further processed and utilized in a variety of industries, including petrochemicals, chemicals, and refining. It can be used as a feedstock for the production of a wide range of chemicals, such as methanol or ammonia, or as a reducing agent in various industrial processes. HyCO plants are essential in supporting these industries by providing a versatile source of hydrogen and carbon monoxide for their processes.

Our TIGER OPTICS™ CO-rekt CW-CRDS analyzers experience no temperature drift or spectral interference. These analyzers require no calibration, obviating the need for complex, costly calibration gas sampling systems, human intervention and frequent, risky movement of cylinders. With no interruptions for maintenance or unplanned shutdowns, the CO-rekt affords extremely low cost of ownership and allows you to operate continuously online. CW-CRDS (Continuous Wave Cavity Ringdown Spectroscopy) analyzers experience no temperature drift or spectral interference. This analyzer requires no calibration, obviating the need for complex, costly calibration gas sampling systems, human intervention and frequent, risky movement of cylinders. With no interruptions for maintenance or unplanned shutdowns, the CO-rekt affords extremely low cost of ownership and allows you to operate continuously online.


Analyzers for Hydrogen Purity Analysis

TIGER OPTICS™ HALO OK
CRDS trace level oxygen with PPT accuracy and aligns with the SEMI F-112 standard for moisture 

TIGER OPTICS™  Spark H2OSpark CH4Spark CO2
Cost-efficient, single-species CRDS with ppb detection for Hydrogen Purity Analysis

TIGER OPTICS™ Prismatic 3
Multi-species, laser-based CRDS analyzer for Hydrogen Purity Analysis to meet SAE J2719 and ISO 14687:2019

TIGER OPTICS™ HALO 3 NH3 • HALO 3 CH2O2 •
HALO 3 COHALO 3 HCl 

Sensitive, single-species CRDS analyzer for Hydrogen Purity Analysis

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EXTREL™ MAX300-LG
Real-Time Quadrupole Mass Spectrometer for monitoring He, N2, Ar, CH4, O2, CH2O and CH2O2

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